Cellulose

Books

Rosenau, T.; Potthast, A; Hell, J (eds.)
“Cellulose science and Technology. Chemistry, analysis and applications”. John Wiley & Sons Inc., Hoboken, USA, 2019, 435 p. ISBN 9781119217672 (Adobe PDF) / 9781119217633 (ePub) / 9781119217589 (hardcover).   

Reviews

  1. Potthast, A.; Rosenau, T.; Kosma, P.
    Adv. Polym. Sci. 2006, 205, 1-48. Polysaccharides II (Klemm, D., ed.), Springer, Heidelberg. Analysis of oxidized functionalities in cellulose.
  2. Rosenau, T.; Potthast, A.; Kosma, P.
    Adv. Polym. Sci. 2006, 205, 153-197. Polysaccharides II (Klemm, D., ed.), Springer, Heidelberg. Trapping of reactive intermediates to study reaction mechanisms in cellulose chemistry.
  3. Potthast, A.; Rosenau, T.; Kosma, P.
    ”Carbonyl and Carboxyl Profiles as Two Novel Parameters in Advanced Cellulose Analytics” in Materials, Chemicals and Energy from Forest Biomass Materials, Chemicals and Energy from Forest Biomass, Argyropoulos, D. (ed.), ACS book series 954, American Chemical Society, 2007, 513-530.
  4. Henniges, U.; Schiehser, S.; Rosenau, T.; Potthast, A.
    Cellulose solubility: Dissolution and analysis of "problematic" cellulose pulps in the solvent system DMAc/LiCl. In: „Cellulose solvents; for analysis, shaping and chemical modification“, ACS Symp. Ser. vol. 1033 (T. Liebert, T. Heinze, K. Edgar, Eds.), American Chemical Society, Washington D.C., 2009, chapter 9, pp 165-177.
  5. Becker, M.; Zweckmair, T.; Forneck, A.; Rosenau, T.; Potthast, A.; Liebner, F.
    J. Chromatogr. A 2013, 1281, 115-126. Evaluation of different derivatisation approaches for GC/MS analysis of carbohydrates in complex matrices of biological and synthetic origin.
  6. Henniges, U.; Vejdovszky, P.; Siller, M.; Jeong, M.-J.; Rosenau, T.; Potthast, A.
    Curr. Chromatogr. 2014, 1(1), 52-68. Finally Dissolved! Activation Procedures to Dissolve Cellulose in DMAc/LiCl Prior to Size Exclusion Chromatography Analysis - A Review.
  7. Potthast, A.; Rosenau, T.; Henniges, U.; Schiehser, S.; Kosma, P.; Saake, B.; Lebioda, S.; Radosta, S.; Vorwerg, W.; Wetzel, H.; Koschella, A.; Heinze, T.; Strobin, G.; Sixta, H.; Strlic, M.; Isogai, A.
    Cellulose 2015, 22(3), 1591 – 1613. Comparison testing of methods for gel permeation chromatography of cellulose: Coming closer to a standard protocol.
  8. Oberlerchner, J. T.; Rosenau, T.; Potthast, A.
    Molecules 2015, 20(6), 10313 – 10341. www.mdpi.com/1420-3049/20/6/10313/pdf. Overview of methods for the direct molar mass determination of cellulose.
  9. Odabas, N.; Henniges, U.; Potthast, A.; Rosenau, T.
    Progr. Mat. Sci. 2016, 83, 574–594. DOI: 10.1016/j.pmatsci.2016.07.006. Cellulosic Fines: Properties and Effects.
  10. French, A.D.; Pérez, S.; Bulone, V.; Rosenau, T.; Gray, D.
    Cellulose. 1-69. In: Encyclopedia of Polymer Science and Technology. John Wiley & Sons, Inc. 2018. DOI: 10.1002/0471440264.pst042.pub2.
  11. Rosenau, T.; Potthast, A.; Hofinger, A.; Bacher, M; Yoneda, Y.; Mereiter, K.; Nakatsubo, F.; Jäger, C.; French, A. D.; Kajiwara, K.
    “Toward a Better Understanding of Cellulose Swelling, Dissolution, and Regeneration on the Molecular Level.”, chapter 5, pp. 99-125. In: Rosenau, T.; Potthast, A; Hell, J (eds.) “Cellulose science and Technology. Chemistry, analysis and applications”. John Wiley & Sons Inc., Hoboken, USA, 2019.

Publications

  1. Röhrling, J.; Potthast, A.; Rosenau, T.; Lange, T.; Ebner, G.; Sixta, H.; Kosma, P. Biomacromolecules 2002, 3, 959-968. A novel method for the determination of carbonyl groups in cellulosics by fluorescence labeling. 1. Method development.
  2. Röhrling, J.; Potthast, A.; Rosenau, T.; Lange, T.; Borgards, A.; Sixta, H.; Kosma, P. Biomacromolecules 2002, 3, 969-975. A novel method for the determination of carbonyl groups in cellulosics by fluorescence labeling. 2. Validation and applications.
  3. Potthast, A.; Röhrling, J.; Rosenau, T.; Borgards, A.; Sixta, H.; Kosma, P. Biomacromolecules 2003, 4 (3), 743-749. A novel method for the determination of carbonyl groups in cellulosics by fluorescence labeling. 3. Monitoring oxidative processes.
  4. Potthast, A.; Schiehser, S.; Rosenau, T.; Sixta, H.; Kosma, P.
    Holzforschung 2004, 58, 597-602. Effect of UV radiation on the carbonyl distribution in different pulps.
  5. Rosenau, T.; Potthast, A.; Kosma, P.; Saariaho, A.-M.; Vuorinen, T.; Sixta, H. Cellulose 2005, 12(1), 43-50. On the nature of carbonyl groups in cellulosic pulps.
  6. Bohrn, R.; Potthast; Schiehser, S.; Rosenau, T.; Sixta, H.; Kosma, P.
    Biomacromol. 2006, 7, 1743-1750. A novel method for the determination of carboxyl profiles in cellulosics by fluorescence labeling. Part I: Method development.
  7. Yoneda, Y.; Mereiter, K.; Jäger, C.; Brecker, L.; Kosma, P.; Rosenau, T.; French, A. J. Am. Chem. Soc. 2008, 130(49), 16678-16690. van der Waals versus Hydrogen-Bonding Forces in a Crystalline Analog of Cellotetraose: Cyclohexyl 4′-O-Cyclohexyl β-d-Cellobioside Cyclohexane Solvate.
  8. Karrasch, A.; Jäger, C.; Karakawa, M.; Nakatsubo, F.; Potthast, A.; Rosenau, T. Cellulose 2009, 16(1), 129-137. Solid-state NMR studies of methyl celluloses. Part 1: Regioselectively substituted celluloses as standards for establishing an NMR data basis.
  9. Potthast, A.; Schiehser, S.; Rosenau, T.; Kostic, M.
    Holzforschung 2009, 63(1), 12-17. Oxidative modifications of cellulose in the periodate system – Reduction and beta-elimination reactions.
  10. Karrasch, A.; Jäger, C.; Saake, B.; Potthast, A.; Rosenau, T.
    Cellulose 2009, 16(6), 1159–1166. DOI 10.1007/s10570-009-9304-2. Solid-state NMR studies of methyl celluloses. Part 2: Determination of degree of substitution and O-6 vs. O-2/O-3 substituent distribution in commercial methyl cellulose samples.
  11. Tot, I.; Müller, Y.; Werner, C.; Rosenau, T.; Potthast, A.
    Holzforschung 2009, 63(6), 657 – 664.A novel, mild and selective methylation of carboxyl groups in cellulosic pulps.
  12. Henniges, U.; Kostic, M.; Borgards, A.; Rosenau, T.; Potthast, A.
    Biomacromolecules 2011, 12(4), 871-879. Dissolution behaviour of different celluloses.
  13. Patel, I.; Ludwig, R.; Haltrich, D.; Rosenau, T.; Potthast, A
    Holzforschung 2011, 65, 475-481. Studies of the chemoenzymatic modification of cellulosic pulps by the laccase-TEMPO system.
  14. Henniges, U.; Okubayashi, S.; Rosenau, T.; Potthast, A. Biomacromolecules 2012, 13(12), 4171-4178. Irradiation of cellulosic pulps: understanding its impact on cellulose oxidation.
  15. Stefanovic, B.; Rosenau, T.; Potthast, A. Carbohydr. Polym. 2013, 92(1), 921-927. Effect of sonochemical treatments on integrity and oxidation state of cellulose.
  16. Henniges, U.; Hasani, M.; Potthast, A.; Westman, G.; Rosenau, T. Materials 2013, 6(5), 1584-1598. Electron beam irradiation of cellulosic materials – opportunities and limitations.
  17. Becker, M.; Liebner, F.; Rosenau, T.; Potthast, A. Talanta, 2013, 115, 642-651. Ethoximation-silylation approach with expanded retention index (ERI) for mono- and disaccharide analysis by GC/MS.
  18. Stefanovic, B.; Pirker, K. F.; Rosenau, T.; Potthast, A. Carbohydr. Polym. 2014, 111, 688-699. Effects of tribochemical treatments on the integrity of cellulose.
  19. Siller, M.; Ahn. K.; Pircher, N.; Rosenau, T.; Potthast, A. Cellulose 2014, 21(5), 3291-3301. Dissolution of rayon fibres for size exclusion chromatography: a challenge.
  20. Siller, M.; Amer, H.; Bacher, M.; Rosenau, T.; Potthast, A. Cellulose 2015, 22(4), 2245-2261. Effects of periodate oxidation on cellulose polymorphs.
  21. Sulaeva, I.; Klinger, K.-M.; Amer, H.; Henniges, U.; Rosenau, T.; Potthast, A.
    Cellulose 2015, 22(6), 3569-3581. Determination of molar mass distributions of highly oxidized dialdehyde cellulose by size exclusion chromatography and asymmetric flow field-flow fractionation.
  22. Nypelö, T.; Amer, H.; Konnerth, J.; Potthast, A.; Rosenau, T. Biomacromolecules 2018, 19(3), 973-979. Self-standing cellulose Janus-type films with aldehyde and carboxyl functionalities.
  23. Hosoya, T.; Bacher, M.; Potthast, A.; Elder, T.; Rosenau, T. Cellulose 2018, 25(7), 3797-3814. Insights into degradation pathways of oxidized anhydroglucose units in cellulose by b-alkoxy-elimination – a combined theoretical and experimental approach.
  24. Oberlerchner, J. T.; Böhmdorfer, S.; Rosenau, T.; Potthast, A. Holzforschung 2018, 72(8), 645-652. A matrix-resistant HPTLC method to quantify monosaccharides in wood-based lignocellulose biorefinery streams.
  25. Ahn, K.; Zaccaron, S.; Zwirchmayr, N. S.; Hettegger, H.; Hofinger, H.; Bacher, M.; Henniges, U.; Hosoya, T.; Potthast, A.; Rosenau, T. Cellulose 2019, 26, 429-444. Yellowing and brightness reversion of celluloses: CO or COOH, who is the culprit?
  26. Ling, Z.; Wang, T.; Makarem, M.; Cintrón, M. S.; Cheng, H. N.; Kang, X.; Bacher, M.; Potthast, A.; Rosenau, T.; King, H.; Delhom, C. D.; Nam, S.; Edwards, J. V.; Kim, S. H.; Xu, F.; French, A.; D. Cellulose 2019, 26(1), 305-328. Effects of ball milling on the structure of cotton cellulose.
  27. Lucia, A.; Van Herwijnen, H. W. G.; Oberlerchner, J. T.; Rosenau, T.; Beaumount, M. ChemSusChem 2019, 12(20), 4679-4684. Resource-saving production of dialdehyde cellulose: Optimization of the process at high-consistency.
  28. Koso, T.; del Cerro, R. D.; Heikkinen, S.; Nypelö, T.; Buffiere, J.; Perea-Buceta, J.; Potthast, A.; Rosenau, T.; Heikkinen, H.; Maaheimo, H.; Isogai, A.; Kilpeläinen, I.; King, A. Cellulose 2020, in press. 2D Assignment and Quantitative Analysis of Cellulose and Oxidized Celluloses using Solution-State NMR Spectroscopy.

Lignin

Reviews

  1. Lucia, A.; van Herwijnen, H. W. G.; Rosenau, T.
    Holzforschung 2020, in press. Wood-based resins and other bio-based binders for the production of mineral wool: a mini-review.
  2. Mimini, V.; Kabrelian, V.†; Fackler, K.; Hettegger, H.; Potthast, A.; Rosenau, T. Holzforschung 2019, 73(1), 117-130. Lignin-Based Foams as Insulation Materials: A Review.

Publications

  1. Gregor, W.; Grabner, G.; Adelwöhrer, C.; Rosenau, T.; Gille, L. J. Org. Chem. 2005, 70(9), 3472-3483. Antioxidant Properties of Natural and Synthetic Chromanol Derivatives: a Study by Fast Kinetics and Electron Spin Resonance Spectroscopy.
  2. Bogolitsyna, A.; Becker, M.; Dupont, A.-L.; Borgards, A.; Götzinger, G.; Rosenau, T.; Potthast, A. J. Chromat. A. 2011, 1218, 8561-8566. Determination of carbohydrate- and lignin-derived components in complex effluents from cellulose processing by capillary electrophoresis with electrospray ionization - mass spectrometric detection.
  3. Liebner, F.; Pour, G.; de la Rosa Arranz, J. M.; Hilscher, A.; Rosenau, T.; Knicker, H.
    Angew. Chem. Int. Ed. 2011, 50(37), A34-A39. Ammonoxidised lignins as slow nitrogen-releasing soil amendments and CO2-binding matrix.
  4. Schrems, M.; Liebner, F.; Betz, M.; Zeilinger, M.; Böhmdorfer, S.; Rosenau, T.; Potthast, A. J. Wood Chem. Technol. 2012, 32(3), 225-237. Understanding the impact of supercritical carbon dioxide on the delignification mechanism during Organosolv pulping: a model compound study.
  5. Bogolitsyna, A.; Becker, M.; Borgards, A.; Liebner, F.; Rosenau, T.; Potthast, A. Holzforschung 2012, 66(8), 917-925. Degradation products of lignocellulosics – comparison and evaluation of different gas chromatographic techniques for a more comprehensive analysis.
  6. Klinger, K.M.; Liebner, F.; Hosoya, T.; Potthast, A.; Rosenau, T. J. Agric. Food Chem. 2013, 61(38), 9015-9026. Ammoxidation of Lignocellulosic Materials: Formation of Nonheterocyclic Nitrogenous Compounds from Monosaccharides.
  7. Klinger, K.M.; Liebner, F.; Fritz, I.; Potthast, A.; Rosenau, T. J. Agric. Food Chem. 2013, 61(38), 9004-9014. Formation and Ecotoxicity of N-Heterocyclic Compounds on Ammoxidation of Mono- and Polysaccharides.
  8. Zweckmair, T.; Becker, M.; Ahn, K.; Hettegger, H.; Kosma, P.; Rosenau, T.; Potthast, A. J. Chromatogr. A, 2014, 1372C, 212-220. A novel method to analyze the degree of acetylation in biopolymers.
  9. Glas, D.; Van Doorslaer, C.; Depuydt, D.; Liebner, F.; Rosenau, T.; Binnemans, K.; De Vos, D. E. J. Chem. Technol. Biotechnol. 2015, 90(10), 1821-1826. DOI: 10.1002/jctb.4492. Lignin Solubility in Non-Imidazolium Ionic Liquids.
  10. Korntner, P.; Sumerskii, I.; Bacher, M.; Rosenau, T.; Potthast, A. Holzforschung 2015, 69(6), 807-814. Characterization of technical lignins by NMR spectroscopy: optimization of functional group analysis by 31P NMR spectroscopy.
  11. Sumerskii, I.; Korntner,P.; Zinovyev, G.; Rosenau, T.; Potthast, A.
    RSC Advances 2015, 5(112), 92732-92742. Fast track for quantitative isolation of lignosulfonates from spent sulfite liquors.
  12. Zinovyev, G.; Sumerskij, I.; Korntner, P.; Sulaeva, I.; Rosenau, T.; Potthast A.
    J. Wood Chem. Technol. 2017, 37(3), 171-183. Molar mass-dependent profiles of functional groups and carbohydrates in kraft lignin.
  13. Sulaeva, I.; Zinovjev, G.; Plankeele, J. M.; Sumerskii, I.; Rosenau, T.; Potthast, A. ChemSusChem 2017, 10, 629-635. Fast track to molar mass distributions of technical lignins.
  14. Sumerskii, I.; Zweckmair, T.; Hettegger, H.; Zinovyev, G.; Bacher, M.; Rosenau, T.; Potthast, A. RSC Advances 2017, 7, 22974-22982. A fast track for the accurate determination of methoxyl and ethoxyl groups in lignin.
  15. Korntner, P.; Schedl, A.; Sumerskii, I.; Zweckmair, T.; Mahler, A.; Rosenau, T.; Potthast, A. ACS Sust. Chem. Eng. 2018, 6(5), 6240-6246. Sulfonic Acid Group Determination in Lignosulfonates by Headspace Gas Chromatography.
  16. Zinovyev, G.; Sulaeva, I.; Podzimek, S.; Rössner, D.; Kilpeläinen, I.; Sumerskii, I.; Rosenau, T.; Potthast, A. ChemSusChem. 2018, 11(18), 3259-3268. Getting closer to absolute molar masses of technical lignins.
  17. Zinovyev, G.; Sumerskii, I.; Rosenau, T.; Balakshin, M.; Potthast, A.
    Molecules 2018, 23, 2223. DOI:10.3390/molecules23092223. Ball milling’s effect on pine milled wood lignin’s structure and molar mass.
  18. Mimini, V.; Sykacek, E.; Ain Syed Hashim, S. N.; Holzweber, J.; Hettegger, H.; Fackler, K.; Potthast, A; Mundigler, N.; Rosenau, T. J. Wood Chem. Technol. 2019, 39, 14-30. Compatibility of Kraft Lignin, Organosolv Lignin and Lignosulfonate with PLA in 3D Printing.
  19. Sulaeva, I.; Vejdovszky, P.; Mahler, K. A.; Rosenau, T.; Potthast, A.
    ACS Sust. Chem. Engin. 2019, 7(1), 216-223. Molar Mass Characterization of Crude Lignosulfonates by Asymmetric Flow Field-Flow Fractionation.
  20. Guggenberger, M.; Potthast, A.; Rosenau, T.; Böhmdorfer, S.
    ChemSusChem 2019, 7(11), 9896-9903. Quantification of Volatiles from Technical Lignins by MHS-SPME-GC-MS.
  21. Musl, O.; Holzlechner, M.; Winklehner, S.; Guebitz, G.; Potthast, A.; Rosenau, T.; Böhmdorfer, S. ACS Sust. Chem. Engin. 2019, 7(18), 15163-15172. Changing the Molecular Structure of Kraft Lignins - Ozone Treatment at Alkaline Conditions.
  22. Mimini, V.; Amer, H.; Hettegger, H.; Bacher, M.; Gebauer, I.; Bischof, R.; Fackler, K.; Potthast, A.; Rosenau, T.
    Holzforschung 2020, 74(2), 203-211. Lignosulfonate-based polyurethane materials via cyclic carbonates: Preparation and characterization.
  23. Balakshin, M.; Capanema, E. A.; Potthast, A.; Rosenau, T.
    Green Chem. 2020, in press. Spruce Milled Wood Lignin: Linear, Branched or Cross-linked?
  24. Musl, O.; Sulaeva, I.; Bacher, M.; Mahler, K. A.; Rosenau, T.; Potthast, A.
    ChemSusChem 2020, in press. Any future high-value use of lignosulfonates needs a thorough characterization of their amphiphilic properties.

Extractions and separations

Reviews

  1. Haimer, E.; Liebner, F.; Potthast, A.; Rosenau, T. Micro- and Nanoparticles from Hemicelluloses. In: Polysaccharide Building Blocks: A Sustainable Approach To the Development of Renewable Materials. Habibi, Y.; Lucia, L.A. (eds.). John Wiley & Sons, Inc., Hoboken, New Jersey, 2012, p. 367 - 386. ISBN: 9780470874196.
  2. Rußler, A.; Bogolitsyna, A.; Zuckerstätter, G.; Potthast, A.; Rosenau, T.
    Chemical Characterisation of Polysaccharides. In: The European Polysaccharide Network of Excellence (EPNOE), Research Initiatives and Results. Navard, P. (ed.). Springer, Wien, 2013, p. 65-90. ISBN 978-3-791-0420-0.

Publications

  1. Sartori, J.; Potthast, A.; Rosenau, T.; Hofinger, A.; Sixta, H.; Kosma, P. Holzforschung 2004, 58, 588-596. Alkaline degradation of model compounds related to beech xylan.
  2. Sjöberg, J.; Potthast, A.; Rosenau, T.; Kosma, P.; Sixta, H.
    Biomacromolecules 2005, 6(6), 3146-3151. Cross-sectional analysis of the polysaccharide composition in cellulosic fiber materials by enzymatic peeling and high-performance capillary zone electrophoresis (HPCE).
  3. Rußler, A.; Potthast, A.; Rosenau, T.; Lange, T.; Saake, B.; Sixta, H.; Kosma, P.
    Holzforschung 2006, 60(5), 467-473. Determination of substituent distribution of viscoses by GPC.
  4. Haimer, E.; Wendland, M.; Potthast, A.; Henniges, U.; Rosenau, T.; Liebner, F.
    J. Supercrit. Fluids 2010, 53, 121-130. Controlled precipitation and purification of hemicellulose from DMSO and DMSO/water mixtures by carbon dioxide as anti-solvent.
  5. Zweckmair, T.; Böhmdorfer, S.; Bogolitsyna, A.; Rosenau, T.; Potthast, A.; Novalin, S. J. Chromatogr. Sci. 2014, 52(2), 169-175. Accurate analysis of formose reaction products by LC-UV: An analytical challenge.
  6. Amer, H.; Nypelö, T.; Sulaeva, I.; Bacher, M.; Henniges, U.; Potthast, A.; Rosenau, T. Biomacromolecules 2016, 17(9), 2972-2980. Structural elucidation of periodate oxidized polysaccharides: Spectroscopic investigation and thermal property of xylan dialdehyde.
  7. Böhmdorfer, S.; Oberlerchner, J. T.; Rosenau, T.; Potthast, A. Curr. Chromatogr. 2016, 3(2), 75-85. Thin Layer Chromatography and the Analysis of Wood Derived Biomass.
  8. Zweckmair, T.; Schiehser, S.; Rosenau, T.; Potthast, A. Carbohydr. Res. 2017, (446/447), 7-12. Improved quantification of monosaccharides in complex lignocellulosic biomass matrices: A gas chromatography-mass spectrometry based approach.